Bis(2,4,6-tri-amino-1,3,5-triazin-1-ium) 2-[bis-(carboxyl-atometh-yl)aza-nium-yl]acetate trihydrate.

ABSTRACT: The title compound, 2C3H7N6 (+)·C6H7NO6 (2-)·3H2O, was obtained by mixing melamine and nitrilo-tri-acetic acid in aqueous solution. There is proton transfer from the nitrilo-triacteic acid to melamine to produce two melaminium cations and an inter-nal proton transfer to generate the [HN(CH2COO)](2-) zwitterion. The melaminium cations are arranged in hydrogen-bonded tapes formed by N-H⋯N inter-actions. These tapes extend parallel to the [010] direction and are stacked parallel to the a axis at a mean separation of 3.3559 (11) Å. Between these tapes lie the anions and lattice water mol-ecules. Further O-H⋯O and N-H⋯O hydrogen bonds exist between the water mol-ecules, the anions, and the melaminium cations, generating a three-dimensional array. The crystal examined was found to be twinned by

SUBMITTER: Hoxha K 

PROVIDER: S-EPMC3884332 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature