Tuning the interactions between electron spins in fullerene-based triad systems.

ABSTRACT: A series of six fullerene-linker-fullerene triads have been prepared by the stepwise addition of the fullerene cages to bridging moieties thus allowing the systematic variation of fullerene cage (C60 or C70) and linker (oxalate, acetate or terephthalate) and enabling precise control over the inter-fullerene separation. The fullerene triads exhibit good solubility in common organic solvents, have linear geometries and are diastereomerically pure. Cyclic voltammetric measurements demonstrate the excellent electron accepting capacity of all triads, with up to 6 electrons taken up per molecule in the potential range between -2.3 and 0.2 V (vs Fc(+)/Fc). No significant electronic interactions between fullerene cages are observed in the ground state indicating that the individual properties of e

SUBMITTER: Lebedeva MA 

PROVIDER: S-EPMC3943482 | biostudies-literature | 2014

REPOSITORIES: biostudies-literature