Superconducting graphene sheets in CaC6 enabled by phonon-mediated interband interactions.

ABSTRACT: There is a great deal of fundamental and practical interest in the possibility of inducing superconductivity in a monolayer of graphene. But while bulk graphite can be made to superconduct when certain metal atoms are intercalated between its graphene sheets, the same has not been achieved in a single layer. Moreover, there is a considerable debate about the precise mechanism of superconductivity in intercalated graphite. Here we report angle-resolved photoelectron spectroscopy measurements of the superconducting graphite intercalation compound CaC6 that distinctly resolve both its intercalant-derived interlayer band and its graphene-derived π* band. Our results indicate the opening of a superconducting gap in the π* band and reveal a substantial contribution to the total electron-phonon-c

SUBMITTER: Yang SL 

PROVIDER: S-EPMC3973042 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature