Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.

ABSTRACT: A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.

SUBMITTER: Zhu Y 

PROVIDER: S-EPMC3985922 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature