Diels-Alder construction of regiodifferentiated meta-amino phenols and derivatives.

ABSTRACT: Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels-Alder and retro-Diels-Alder sequence with assorted acetylenic dienophiles to afford a range of aromatic products.

SUBMITTER: Weaver MG 

PROVIDER: S-EPMC3993616 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature