Recyclable polystyrene-supported siloxane-transfer agent for palladium-catalyzed cross-coupling reactions.

ABSTRACT: The rational design, synthesis, and validation of a significantly improved insoluble polymer-supported siloxane-transfer agent has been achieved that permits efficient palladium-catalyzed cross-coupling reactions. The cross-linked polystyrene support facilitates product purification with excellent siloxane recycling. Drawbacks of a previous polymer-supported siloxane-transfer agent, relating to reaction efficiency and polymer stability after repeated cycles, have been addressed.

SUBMITTER: Nguyen MH 

PROVIDER: S-EPMC3993864 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature