Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).

ABSTRACT: Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation can be synthesized with high enantiomeric excess.

SUBMITTER: Le H 

PROVIDER: S-EPMC3998767 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature