Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates.

ABSTRACT: Reported are complexes of the formula Fe(dithiolate)(CO)₂(diphos) and their use to prepare homo- and heterobimetallic dithiolato derivatives. The starting iron dithiolates were prepared by a one-pot reaction of FeCl₂ and CO with chelating diphosphines and dithiolates, where dithiolate = S₂(CH₂)₂^2- (edt^2-), S₂(CH₂)₃^2- (pdt^2-), S₂(CH₂)₂(C(CH₃)₂)^2- (Me₂pdt^2-) and diphos = cis-C₂H₂(PPh₂)₂ (dppv), C₂H₄(PPh₂)₂ (dppe), C₆H₄(PPh₂)₂ (dppbz), C

SUBMITTER: Carroll ME 

PROVIDER: S-EPMC3999794 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature