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1,10-Phenanthroline-5,6-dione ethanol monosolvate.

ABSTRACT: In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051?(1)?Å. In the crystal, mol-ecules are linked by O-H?N and weak C-H?O hydrogen bonds, forming supra-molecular chains propagating along [110]. ?-? stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-centroid separations being 3.6226?(11) and 3.7543?(11)?Å.

SUBMITTER: Dai JW

PROVIDER: S-EPMC4011276 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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1,10-Phenanthroline-5,6-dione ethanol monosolvate.

Dai Jing-Wei JW Li Zhao-Yang ZY Sato Osamu O

Acta crystallographica. Section E, Structure reports online 20140418 Pt 5

In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051 (1) Å. In the crystal, mol-ecules are linked by O-H⋯N and weak C-H⋯O hydrogen bonds, forming supra-molecular chains propagating along [110]. π-π stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-centroid separations being 3.6226 (11) and 3.7543 (11) Å. ...[more]

PMID: 24860377

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