Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates.

ABSTRACT: Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral Palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple readily available starting materials.

SUBMITTER: Ardolino MJ 

PROVIDER: S-EPMC4019443 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature