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Vanadium-Catalyzed C(sp3)-H Fluorination Reactions.


ABSTRACT: Vanadium(III) oxide catalyzes the direct fluorination of C(sp3)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction byproduct can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and L-menthone selectively.

SUBMITTER: Xia JB 

PROVIDER: S-EPMC4067045 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature