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Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.

ABSTRACT: By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.

SUBMITTER: DeGuire SM 

PROVIDER: S-EPMC4096701 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.

DeGuire Sean M SM   Ma Shutao S   Sulikowski Gary A GA  

Angewandte Chemie (International ed. in English) 20110907 42

By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide. ...[more]

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