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Detection of volatile organic compounds by weight-detectable sensors coated with metal-organic frameworks.


ABSTRACT: Detection of volatile organic compounds (VOCs) using weight-detectable quartz microbalance and silicon-based microcantilever sensors coated with crystalline metal-organic framework (MOF) thin films is described in this paper. The thin films of two MOFs were grown from COOH-terminated self-assembled monolayers onto the gold electrodes of sensor platforms. The MOF layers worked as the effective concentrators of VOC gases, and the adsorption/desorption processes of the VOCs could be monitored by the frequency changes of weight-detectable sensors. Moreover, the MOF layers provided VOC sensing selectivity to the weight-detectable sensors through the size-selective adsorption of the VOCs within the regulated nanospace of the MOFs.

SUBMITTER: Yamagiwa H 

PROVIDER: S-EPMC4150105 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Detection of volatile organic compounds by weight-detectable sensors coated with metal-organic frameworks.

Yamagiwa Hiroki H   Sato Seiko S   Fukawa Tadashi T   Ikehara Tsuyoshi T   Maeda Ryutaro R   Mihara Takashi T   Kimura Mutsumi M  

Scientific reports 20140901


Detection of volatile organic compounds (VOCs) using weight-detectable quartz microbalance and silicon-based microcantilever sensors coated with crystalline metal-organic framework (MOF) thin films is described in this paper. The thin films of two MOFs were grown from COOH-terminated self-assembled monolayers onto the gold electrodes of sensor platforms. The MOF layers worked as the effective concentrators of VOC gases, and the adsorption/desorption processes of the VOCs could be monitored by th  ...[more]

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