Enhancement of platinum mass activity on the surface of polymer-wrapped carbon nanotube-based fuel cell electrocatalysts.

ABSTRACT: Cost reduction and improved durability are the two major targets for accelerating the commercialization of polymer electrolyte membrane fuel cells (PEFCs). To achieve these goals, the development of a novel method to fabricate platinum (Pt)-based electrocatalysts with a high mass activity, deposited on durable conductive support materials, is necessary. In this study, we describe a facile approach to grow homogeneously dispersed Pt nanoparticles (Pt) with a narrow diameter distribution in a highly controllable fashion on polymer-wrapped carbon nanotubes (CNTs). A PEFC cell employing a composite with the smallest Pt nanoparticle size (2.3 nm diameter) exhibited a ~8 times higher mass activity compared to a cell containing Pt with a 3.7 nm diameter. This is the first example of the diamter c

SUBMITTER: Hafez IH 

PROVIDER: S-EPMC4164040 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature