Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.

ABSTRACT: This article describes the synthesis and characterization of several low-spin iron(II) complexes that coordinate hydrazine (N(2)H(4)), hydrazido (N(2)H(3)(-)), and ammonia. The sterically encumbered tris(di-meta-terphenylphosphino)borate ligand, [PhBP(mter)(3)](-), is introduced to provide access to species that cannot be stabilized with the [PhBP(Ph)(3)](-) ligand ([PhBP(R)(3)](-) = PhB(CH(2)PR(2))(3)(-)). Treatment of [PhBP(mter)(3)]FeMe with hydrazine generates the unusual 5-coordinate hydrazido complex [PhBP(mter)(3)]Fe(η(2)-N(2)H(3)) (1), in which the hydrazido serves as an L(2)X-type ligand. Upon coordination of an L-type ligand, the hydrazido shifts to an LX-type ligand, generating [PhBP(mter)(3)]Fe(L)(η(2)-N(2)H(3)) (L = N(2)H(4) (2) or NH(3) (3)). In contrast, treatment of [PhBP(P

SUBMITTER: Saouma CT 

PROVIDER: S-EPMC4167049 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature