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A piperidine chiron for the Veratrum alkaloids.

ABSTRACT: A Veratrum piperidine chiron was prepared over 11 steps (7.9% yield) from (-)-citronellal. Three methods for the installation of the propargylic side chain onto a cyclic enamide are presented.

SUBMITTER: Taber DF 

PROVIDER: S-EPMC4226469 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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A piperidine chiron for the Veratrum alkaloids.

Taber Douglass F DF   DeMatteo Peter W PW  

The Journal of organic chemistry 20120413 9

A Veratrum piperidine chiron was prepared over 11 steps (7.9% yield) from (-)-citronellal. Three methods for the installation of the propargylic side chain onto a cyclic enamide are presented. ...[more]

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