Luminescence color switching of supramolecular assemblies of discrete molecular decanuclear gold(I) sulfido complexes.

ABSTRACT: A series of discrete decanuclear gold(I) μ(3)-sulfido complexes with alkyl chains of various lengths on the aminodiphosphine ligands, [Au(10){Ph(2)PN(C(n)H2(n+1))PPh(2)}(4)(μ(3)-S)(4)](ClO(4))(2), has been synthesized and characterized. These complexes have been shown to form supramolecular nanoaggregate assemblies upon solvent modulation. The photoluminescence (PL) colors of the nanoaggregates can be switched from green to yellow to red by varying the solvent systems from which they are formed. The PL color variation was investigated and correlated with the nanostructured morphological transformation from the spherical shape to the cube as observed by transmission electron microscopy and scanning electron microscopy. Such variations in PL colors have not been observed in their analogous c

SUBMITTER: Hau FK 

PROVIDER: S-EPMC4234610 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature