Synergistic strengthening of polyelectrolyte complex membranes by functionalized carbon nanotubes and metal ions.

ABSTRACT: Hydrophilic polymers have garnered much attention due to their critical roles in various applications such as molecular separation membranes, bio-interfaces, and surface engineering. However, a long-standing problem is that their mechanical properties usually deteriorate at high relative humidity (RH). Through the simultaneous incorporation of functionalized carbon nanotubes and copper ions (Cu(2+)), this study introduces a facile method to fabricate high strength polyelectrolyte complex nanohybrid membranes resistant to high RH (90%). For example, the tensile strength of the nanohybrid membranes is 55 MPa at 90% RH (80% of the original value at 30% RH). These results are explained by copper ions depressing the swelling degree of the membrane, and functionalized carbon nanotubes promoting

SUBMITTER: Liu T 

PROVIDER: S-EPMC4293594 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature