A carbohydrate approach for the formal total synthesis of (-)-aspergillide C.

ABSTRACT: An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.

SUBMITTER: Srihari P 

PROVIDER: S-EPMC4311580 | biostudies-literature | 2014

REPOSITORIES: biostudies-literature