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Crystal structure of (E)-4-{1-[2-(car-bamo-thio-yl)hydrazin-1-yl-idene]ethyl}phenyl 4-methyl-benzoate.

ABSTRACT: The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent mol-ecules, A and B, with different conformations: in mol-ecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamo-thio-ylhydrazono groups are 71.12 (9) and 5.95 (8)°, respectively. The corresponding angles in mol-ecule B are 50.56 (12) and 26.43 (11)°, respectively. Both mol-ecules feature an intra-molecular N-H⋯N hydrogen bond, which closes an S(5) ring. In the crystal, mol-ecules are linked by N-H⋯O, N-H⋯S and C-H⋯O hydrogen bonds, generating a three-dimensional network.

SUBMITTER: Mani KA 

PROVIDER: S-EPMC4331904 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of (E)-4-{1-[2-(car-bamo-thio-yl)hydrazin-1-yl-idene]ethyl}phenyl 4-methyl-benzoate.

Mani Karthik Ananth KA   Viswanathan Vijayan V   Narasimhan S S   Velmurugan Devadasan D  

Acta crystallographica. Section E, Crystallographic communications 20150101 Pt 1

The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent mol-ecules, A and B, with different conformations: in mol-ecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamo-thio-ylhydrazono groups are 71.12 (9) and 5.95 (8)°, respectively. The corresponding angles in mol-ecule B are 50.56 (12) and 26.43 (11)°, respectively. Both mol-ecules feature an intra-molecular N-H⋯N hydrogen bond, which closes an S(5) ring. In the crystal, mo  ...[more]

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