Neutral poly-/perfluoroalkyl substances in air and snow from the Arctic.

ABSTRACT: Levels of neutral poly-/perfluoroalkyl substances (nPFASs) in air and snow collected from Ny-Ålesund were measured and their air-snow exchange was determined to investigate whether they could re-volatilize into the atmosphere driven by means of air-snow exchange. The total concentration of 12 neutral PFASs ranged from 6.7 to 39 pg m(-3) in air and from 330 to 690 pg L(-1) in snow. A significant log-linear relationship was observed between the gas/particle partition coefficient and vapor pressure of the neutral PFASs. For fluorotelomer alcohol (FTOHs) and fluorotelomer acrylates (FTAs), the air-snow exchange fluxes were positive, indicating net evaporative from snow into air, while net deposition into snow was observed for perfluorooctane sulfonamidoethanols (Me/EtFOSEs) in winter and sprin

SUBMITTER: Xie Z 

PROVIDER: S-EPMC4352854 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature