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Crystal structure of aquadioxido(2-{[(2-oxido-ethyl)-imino]-meth-yl}phenol-ato-?(3) O,N,O')molybdenum(VI).

ABSTRACT: The mononuclear title complex, [Mo(C9H9NO2)O2(H2O)], contains an Mo(VI) atom in a distorted octa-hedral coordination sphere defined by an Mo=O and an Mo-(OH2) bond to the axial ligands and two Mo-O bonds to phenolate and alcoholate O atoms, another Mo=O bond and one Mo-N bond to the imino N atom in the equatorial plane. The five-membered metalla-ring shows an envelope conformation. In the crystal, individual mol-ecules are connected into a layered arrangement parallel to (100) by means of O-H?O hydrogen bonds involving the water mol-ecule as a donor group and the O atoms of neighbouring complexes as acceptor atoms. These inter-actions lead to the formation of a three-dimensional network.

SUBMITTER: Parimala S 

PROVIDER: S-EPMC4384576 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of aquadioxido(2-{[(2-oxido-ethyl)-imino]-meth-yl}phenol-ato-κ(3) O,N,O')molybdenum(VI).

Parimala Sowmianarayanan S   Selvam Parasuraman P  

Acta crystallographica. Section E, Crystallographic communications 20150124 Pt 2

The mononuclear title complex, [Mo(C9H9NO2)O2(H2O)], contains an Mo(VI) atom in a distorted octa-hedral coordination sphere defined by an Mo=O and an Mo-(OH2) bond to the axial ligands and two Mo-O bonds to phenolate and alcoholate O atoms, another Mo=O bond and one Mo-N bond to the imino N atom in the equatorial plane. The five-membered metalla-ring shows an envelope conformation. In the crystal, individual mol-ecules are connected into a layered arrangement parallel to (100) by means of O-H⋯O  ...[more]

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