Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

ABSTRACT: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

SUBMITTER: Nawaz S 

PROVIDER: S-EPMC4384606 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature