Stoichiometric control of DNA-grafted colloid self-assembly.

ABSTRACT: There has been considerable interest in understanding the self-assembly of DNA-grafted nanoparticles into different crystal structures, e.g., CsCl, AlB2, and Cr3Si. Although there are important exceptions, a generally accepted view is that the right stoichiometry of the two building block colloids needs to be mixed to form the desired crystal structure. To incisively probe this issue, we combine experiments and theory on a series of DNA-grafted nanoparticles at varying stoichiometries, including noninteger values. We show that stoichiometry can couple with the geometries of the building blocks to tune the resulting equilibrium crystal morphology. As a concrete example, a stoichiometric ratio of 3:1 typically results in the Cr3Si structure. However, AlB2 can form when appropriate building b

SUBMITTER: Vo T 

PROVIDER: S-EPMC4413314 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature