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Crystal structure of tricarbon-yltris(pyri-dine-κN)rhenium(I) tetra-fluorido-borate.

ABSTRACT: In the title compound, [Re(C6H5N)3(CO)3]BF4, the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C-H⋯F hydrogen bonds and C-H⋯π inter-actions, forming a three-dimensional framework. The F atoms of the BF4 anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11).

SUBMITTER: Ikotun AA

PROVIDER: S-EPMC4420038 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Crystal structure of tricarbon-yltris(pyri-dine-κN)rhenium(I) tetra-fluorido-borate.

Ikotun Adebomi A AA Coogan Micheal P MP Owoseni Abimbola A AA Bhuvanesh Nattamai N Egharevba Gabriel O GO

Acta crystallographica. Section E, Crystallographic communications 20150411 Pt 5

In the title compound, [Re(C6H5N)3(CO)3]BF4, the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C-H⋯F hydrogen bonds and C-H⋯π inter-actions, forming a three-dimensional framework. The F atoms of the BF4 anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11). ...[more]

PMID: 25995887

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