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Crystal structure of μ-oxido-1,1'κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-penta-methyl-cyclo-penta-dien-yl]-trianglo-trititanium(IV)}.

ABSTRACT: The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η(5)-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a penta-methyl-cyclo-penta-dienyl ligand linked in an η(5)-coordination fashion, while three bridging O atoms fill the other three sites.

SUBMITTER: Perez-Redondo A

PROVIDER: S-EPMC4438812 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature

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Crystal structure of μ-oxido-1,1'κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-penta-methyl-cyclo-penta-dien-yl]-trianglo-trititanium(IV)}.

Pérez-Redondo Adrián A Martín Avelino A

Acta crystallographica. Section E, Crystallographic communications 20150321 Pt 4

The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η(5)-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a penta-methyl-cyclo-penta-dienyl ligand linked in an η(5)-coordination fashion, while three bridging O atoms fill the other three sites. ...[more]

PMID: 26029420

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