Control of Photoluminescence of Carbon Nanodots via Surface Functionalization using Para-substituted Anilines.

ABSTRACT: Carbon nanodots (C-dots) are a kind of fluorescent carbon nanomaterials, composed of polyaromatic carbon domains surrounded by amorphous carbon frames, and have attracted a great deal of attention because of their interesting properties. There are still, however, challenges ahead such as blue-biased photoluminescence, spectral broadness, undefined energy gaps and etc. In this report, we chemically modify the surface of C-dots with a series of para-substituted anilines to control their photoluminescence. Our surface functionalization endows our C-dots with new energy levels, exhibiting long-wavelength (up to 650 nm) photoluminescence of very narrow spectral widths. The roles of para-substituted anilines and their substituents in developing such energy levels are thoroughly studied by using

SUBMITTER: Kwon W 

PROVIDER: S-EPMC4517466 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature