Rechargeable magnesium-ion battery based on a TiSe2-cathode with d-p orbital hybridized electronic structure.

ABSTRACT: Rechargeable ion-batteries, in which ions such as Li(+) carry charges between electrodes, have been contributing to the improvement of power-source performance in a wide variety of mobile electronic devices. Among them, Mg-ion batteries are recently attracting attention due to possible low cost and safety, which are realized by abundant natural resources and stability of Mg in the atmosphere. However, only a few materials have been known to work as rechargeable cathodes for Mg-ion batteries, owing to strong electrostatic interaction between Mg(2+) and the host lattice. Here we demonstrate rechargeable performance of Mg-ion batteries at ambient temperature by selecting TiSe2 as a model cathode by focusing on electronic structure. Charge delocalization of electrons in a metal-ligand unit thr

SUBMITTER: Gu Y 

PROVIDER: S-EPMC4521182 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature