Elucidating the role of disorder and free-carrier recombination kinetics in CH3NH3PbI3 perovskite films.

ABSTRACT: Apart from broadband absorption of solar radiation, the performance of photovoltaic devices is governed by the density and mobility of photogenerated charge carriers. The latter parameters indicate how many free carriers move away from their origin, and how fast, before loss mechanisms such as carrier recombination occur. However, only lower bounds of these parameters are usually obtained. Here we independently determine both density and mobility of charge carriers in a perovskite film by the use of time-resolved terahertz spectroscopy. Our data reveal the modification of the free carrier response by strong backscattering expected from these heavily disordered perovskite films. The results for different phases and different temperatures show a change of kinetics from two-body recombination

SUBMITTER: La-O-Vorakiat C 

PROVIDER: S-EPMC4532878 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature