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Fullerene-Structured MoSe2 Hollow Spheres Anchored on Highly Nitrogen-Doped Graphene as a Conductive Catalyst for Photovoltaic Applications.


ABSTRACT: A conductive catalyst composed of fullerene-structured MoSe2 hollow spheres and highly nitrogen-doped graphene (HNG-MoSe2) was successfully synthesized via a wet chemical process. The small molecule diethylenetriamine, which was used during the process, served as a surfactant to stabilize the fullerene-structured MoSe2 hollow spheres and to provide a high content of nitrogen heteroatoms for graphene doping (ca. 12% N). The superior synergistic effect between the highly nitrogen-doped graphene and the high surface-to-volume ratio MoSe2 hollow spheres afforded the HNG-MoSe2 composite high conductivity and excellent catalytic activity as demonstrated by cyclic voltammetry, electrochemical impedance spectroscopy and Tafel measurements. A dye-sensitized solar cell (DSSC) prepared with HNG-MoSe2

SUBMITTER: Bi E 

PROVIDER: S-EPMC4538603 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature