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Photoinduced 1,2,3,4-tetrahydropyridine ring conversions.

ABSTRACT: Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O2 if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O2. In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.

SUBMITTER: Turovska B

PROVIDER: S-EPMC4660982 | biostudies-literature | 2015

REPOSITORIES: biostudies-literature

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Photoinduced 1,2,3,4-tetrahydropyridine ring conversions.

Turovska Baiba B Lund Henning H Lūsis Viesturs V Lielpētere Anna A Liepiņš Edvards E Beljakovs Sergejs S Goba Inguna I Stradiņš Jānis J

Beilstein journal of organic chemistry 20151111

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O2 if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O2. In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions. ...[more]

PMID: 26664638

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