Mechanistic Insights into Two-Phase Radical C-H Arylations.

ABSTRACT: Kinetic, spectroscopic, and computational studies of radical C-H arylations highlight the interplay between chemical and physical rate processes in these multiphase reactions. Anomalous concentration dependences observed here may be reconciled by considering the role of phase transfer processes that mediate concentrations in each phase. In addition, understanding interactions through phase boundaries enables their use in optimization of reaction performance.

SUBMITTER: Baxter RD 

PROVIDER: S-EPMC4665085 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature