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Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu).

ABSTRACT: In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetra-hedral coordination environment with C-E-C (E = Si, Ge) angles in the range 104.47 (5)-114.67 (5)°. The mol-ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol-ecules are combined to dimers by six T-shaped C-H⋯π inter-actions, forming sixfold phenyl embraces (6PE).

SUBMITTER: Zaitsev KV

PROVIDER: S-EPMC4719953 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu).

Zaitsev Kirill V KV Zaitseva Galina S GS Karlov Sergey S SS Korlyukov Alexander A AA

Acta crystallographica. Section E, Crystallographic communications 20151206 Pt 12

In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetra-hedral coordination environment with C-E-C (E = Si, Ge) angles in the range 104.47 (5)-114.67 (5)°. The mol-ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol-ecules are combined to dimers by six T-shaped C-H⋯π inter-actions, forming sixfold phenyl embraces (6PE). ...[more]

PMID: 26870472

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