Ion transport in complex layered graphene-based membranes with tuneable interlayer spacing.

ABSTRACT: Investigation of the transport properties of ions confined in nanoporous carbon is generally difficult because of the stochastic nature and distribution of multiscale complex and imperfect pore structures within the bulk material. We demonstrate a combined approach of experiment and simulation to describe the structure of complex layered graphene-based membranes, which allows their use as a unique porous platform to gain unprecedented insights into nanoconfined transport phenomena across the entire sub-10-nm scales. By correlation of experimental results with simulation of concentration-driven ion diffusion through the cascading layered graphene structure with sub-10-nm tuneable interlayer spacing, we are able to construct a robust, representative structural model that allows the establish

SUBMITTER: Cheng C 

PROVIDER: S-EPMC4758742 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature