Intramolecular interactions in the polar headgroup of sphingosine: serinol.
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ABSTRACT:
SUBMITTER: Loru D
PROVIDER: S-EPMC4766959 | biostudies-literature | 2016 Mar
REPOSITORIES: biostudies-literature
Publications
Intramolecular interactions in the polar headgroup of sphingosine: serinol.
Loru Donatella D Peña Isabel I Alonso José L JL Sanz M Eugenia ME
Chemical communications (Cambridge, England) 20160301 18
The intramolecular interactions in the lipid sphingosine have been elucidated through the investigation of the amino alcohol serinol which mimics its polar headgroup. Intricate networks of intramolecular hydrogen bonds involving the hydroxyl groups and the amino group contribute to the stabilisation of five different conformations observed in the broadband rotational spectrum. ...[more]
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