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Enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes.


ABSTRACT: The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.

SUBMITTER: Saleh N 

PROVIDER: S-EPMC4793888 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature