Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.

ABSTRACT: A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α-arylated ketones without the use of transition metals from readily accessible alkenes.

SUBMITTER: Brown M 

PROVIDER: S-EPMC4797713 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature