X-ray Excited Optical Fluorescence and Diffraction Imaging of Reactivity and Crystallinity in a Zeolite Crystal: Crystallography and Molecular Spectroscopy in One.

ABSTRACT: Structure-activity relationships in heterogeneous catalysis are challenging to be measured on a single-particle level. For the first time, one X-ray beam is used to determine the crystallographic structure and reactivity of a single zeolite crystal. The method generates ?m-resolved X-ray diffraction (?-XRD) and X-ray excited optical fluorescence (?-XEOF) maps of the crystallinity and Brønsted reactivity of a zeolite crystal previously reacted with a styrene probe molecule. The local gradients in chemical reactivity (derived from ?-XEOF) were correlated with local crystallinity and framework Al content, determined by ?-XRD. Two distinctly different types of fluorescent species formed selectively, depending on the local zeolite crystallinity. The results illustrate the potential of this approach to resolve the crystallographic structure of a porous material and its reactivity in one experiment via X-ray induced fluorescence of organic molecules formed at the reactive centers.

SUBMITTER: Ristanovic Z 

PROVIDER: S-EPMC4950131 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature