Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.

ABSTRACT: We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters and carried out on gram scale as well as under flow conditions.

SUBMITTER: Mfuh AM 

PROVIDER: S-EPMC4974080 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature