Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes.

ABSTRACT: The stereochemical outcome of reactions of chiral nucleophilic trisubstituted acetonide radicals with electron-deficient alkenes is dictated by a delicate balance between destabilizing non-bonding interactions and stabilizing hydrogen-bonding between substituents on the α and β carbons.

SUBMITTER: Tao DJ 

PROVIDER: S-EPMC4978530 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature