Redetermination of ruizite, Ca2Mn(3+) 2[Si4O11(OH)2](OH)2·2H2O.

ABSTRACT: The crystal structure of ruizite, ideally Ca2Mn(3+) 2[Si4O11(OH)2](OH)2·2H2O [dicalcium dimanganese(III) tetra-silicate tetra-hydroxide dihydrate] was first determined in space group A2 with an isotropic displacement parameter model (R = 5.6%) [Hawthorne (1984 ▸). Tschermaks Mineral. Petrogr. Mitt. 33, 135-146]. A subsequent refinement in space group C2/m with anisotropic displacement parameters for non-H atoms converged with R = 8.4% [Moore et al. (1985 ▸). Am. Mineral. 70, 171-181]. The current study reports a redetermination of the ruizite structure by means of single-crystal X-ray diffraction data of a natural sample from the Wessels mine, Kalahari Manganese Field, Northern Cape Province, South Africa. Our data (R 1 = 3.0%) confirm that the space group of ruizite is that of the first s

SUBMITTER: Fendrich KV 

PROVIDER: S-EPMC4992915 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature