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Multishelled NiO Hollow Microspheres for High-performance Supercapacitors with Ultrahigh Energy Density and Robust Cycle Life.


ABSTRACT: Multishelled NiO hollow microspheres for high-performance supercapacitors have been prepared and the formation mechanism has been investigated. By using resin microspheres to absorb Ni(2+) and subsequent proper calcinations, the shell numbers, shell spacing and exterior shell structure were facilely controlled via varying synthetic parameters. Particularly, the exterior shell structure that accurately associated with the ion transfer is finely controlled by forming a single shell or closed exterior double-shells. Among multishelled NiO hollow microspheres, the triple-shelled NiO with an outer single-shelled microspheres show a remarkable capacity of 1280 F g(-1) at 1 A g(-1), and still keep a high value of 704 F g(-1) even at 20 A g(-1). The outstanding performances are attributed to its f

SUBMITTER: Qi X 

PROVIDER: S-EPMC5018958 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature