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Crystal structure of μ-4-oxidobenzoato-κ²O¹:O⁴-bis-[bis-(1,10-phenanthroline-κ²N,N')copper(II)] bis-(4-hy-droxy-benzoate) 7.5-hydrate.

ABSTRACT: The title hydrated complex, [Cu₂(C₇H₄O₃)(C₁₂H₈N₂)₄](C₇H₅O₃)₂·7.5H₂O, is composed of dinuclear Cu^II complex cations, noncoordinating 4-hy-droxy-benzoate anions and water mol-ecules of crystallization. In the dinuclear complex cation, the Cu^II ions are bridged by a 4-oxidobenzoate ligand and thus each metal ion is five-coordinated by two chelating 1,10-phenanthroline (phen) mol-ecules and one anionic O atom in a distorted trigonal-bipyramid geometry. In the crystal, aromatic π-π stacking occurs between phen rings of neighbouring dinuclear Cu^II complex cations, forming two-dimensional supra-molecular systems parallel to (100).

SUBMITTER: Su JR

PROVIDER: S-EPMC5050762 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of μ-4-oxidobenzoato-κ2O1:O4-bis-[bis-(1,10-phenanthroline-κ2N,N')copper(II)] bis-(4-hy-droxy-benzoate) 7.5-hydrate.

Su Jian-Rong JR Li Yu Y

Acta crystallographica. Section E, Crystallographic communications 20160905 Pt 10

The title hydrated complex, [Cu2(C7H4O3)(C12H8N2)4](C7H5O3)2·7.5H2O, is composed of dinuclear CuII complex cations, noncoordinating 4-hy-droxy-benzoate anions and water mol-ecules of crystallization. In the dinuclear complex cation, the CuII ions are bridged by a 4-oxidobenzoate ligand and thus each metal ion is five-coordinated by t ...[more]

PMID: 27746927

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