Synthesis and crystal structure of 4-(2-ammonio-eth-yl)morpholin-4-ium di-chlorido-diiodido-cadmate/chlorido-tri-iodido-cadmate (0.90/0.10).

ABSTRACT: The crystal structure of the title compound, (C₆H₁₆N₂O)[CdCl_1.90I_2.10], a new organic-inorganic hybrid salt synthesized in the form of single crystals, consists of discrete statistically distributed di-chlorido-diiodido-cadmate/chlorido-tri-iodido-cadmate anions (occupancy ratio 0.90:0.10) and 4-(2-ammonio-eth-yl)morpholin-4-ium cations, [NH₃(CH₂)₂NH(CH₂)₄O]²⁺. The cations are linked by inter-molecular N-H⋯O hydrogen bonds, forming corrugated chains extending parallel to the c axis. The [CdCl_1.90I_2.10]^2- tetra-halidocadmate anions lie between the chains to maximize the electrostatic inter-actions and are connected with the organic

SUBMITTER: Mahbouli Rhouma N 

PROVIDER: S-EPMC5050764 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature