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Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate.

ABSTRACT: (1)H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.

SUBMITTER: Massena CJ 

PROVIDER: S-EPMC5065062 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate.

Massena Casey J CJ   Riel Asia Marie S AM   Neuhaus George F GF   Decato Daniel A DA   Berryman Orion B OB  

Chemical communications (Cambridge, England) 20150101 8

(1)H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases. ...[more]