Formation of xenon-nitrogen compounds at high pressure.

ABSTRACT: Molecular nitrogen exhibits one of the strongest known interatomic bonds, while xenon possesses a closed-shell electronic structure: a direct consequence of which renders both chemically unreactive. Through a series of optical spectroscopy and x-ray diffraction experiments, we demonstrate the formation of a novel van der Waals compound formed from binary Xe-N₂ mixtures at pressures as low as 5 GPa. At 300 K and 5 GPa Xe(N₂)₂-I is synthesised, and if further compressed, undergoes a transition to a tetragonal Xe(N₂)₂-II phase at 14 GPa; this phase appears to be unexpectedly stable at least up to 180 GPa even after heating to above 2000 K. Raman spectroscopy measurements indicate a distinct weakening of the intramolecular bond of the nitr

SUBMITTER: Howie RT 

PROVIDER: S-EPMC5066244 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature