Direct observation of photocarrier electron dynamics in C₆₀ films on graphite by time-resolved two-photon photoemission.

ABSTRACT: Time-resolved two-photon photoemission (TR-2PPE) spectroscopy is employed to probe the electronic states of a C₆₀ fullerene film formed on highly oriented pyrolytic graphite (HOPG), acting as a model two-dimensional (2D) material for multi-layered graphene. Owing to the in-plane sp²-hybridized nature of the HOPG, the TR-2PPE spectra reveal the energetics and dynamics of photocarriers in the C₆₀ film: after hot excitons are nascently formed in C₆₀ via intramolecular excitation by a pump photon, they dissociate into photocarriers of free electrons and the corresponding holes, and the electrons are subsequently detected by a probe photon as photoelectrons. The decay rate of photocarriers from the C₆₀ film into the HOPG is evaluated to be

SUBMITTER: Shibuta M 

PROVIDER: S-EPMC5075791 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature