Synthesis, Properties, and Light-Emitting Electrochemical Cell (LEEC) Device Fabrication of Cationic Ir(III) Complexes Bearing Electron-Withdrawing Groups on the Cyclometallating Ligands.

ABSTRACT: The structure-property relationship study of a series of cationic Ir(III) complexes in the form of [Ir(C^N)₂(dtBubpy)]PF₆ [where dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridine and C^N = cyclometallating ligand bearing an electron-withdrawing group (EWG) at C₄ of the phenyl substituent, i.e., -CF₃ (1), -OCF₃ (2), -SCF₃ (3), -SO₂CF₃ (4)] has been investigated. The physical and optoelectronic properties of the four complexes were comprehensively characterized, including by X-ray diffraction analysis. All the complexes exhibit quasireversible dtBubpy-based reductions from -1.29 to -1.34 V (vs SCE). The oxidation processes are likewise quasireversible (metal + C^N ligand) and are between 1.54 and 1.72 V (vs SC

SUBMITTER: Pal AK 

PROVIDER: S-EPMC5080635 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature