Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites.

ABSTRACT: Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift of the bandgap and dual emission in perovskites is still lacking. In this direction, we investigated the extraordinary photoluminescence behavior of three representatives of this important class of photonic materials, that is, CH₃NH₃PbI₃, CH₃NH₃PbBr₃, and CH(NH₂)₂PbBr₃, which emerged from our thorough studies of the effects of temperature on their bandgap and emission decay dynamics using time-integrated and time-resolved photoluminescence s

SUBMITTER: Dar MI 

PROVIDER: S-EPMC5091363 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature