Three phenanthroline-metal complexes with topologically similar but geometrically different conformations.

ABSTRACT: The structures of three related complexes of general formula M(pds)(nab)₂ [pds is the peroxodi-sulfate anion and nab is an nitro-gen-containing aromatic base], viz. bis(2,9-dimethyl-1,10-phenanthroline-κ²N,N')(peroxodi-sulfato-κ²O,O')cadmium, [Cd(S₂O₈)(C₁₄H₁₂N₂)₂], (V), bis-(3,4,7,8-tetra-methy-1,10-phenanthroline-κ²N,N')(peroxodi-sulfato-κ²O,O')zinc, [Zn(S₂O₈)(C₁₆H₁₆N₂)₂], (VI), and bis-(3,4,7,8-tetra-methy-1,10-phenanthroline-κ²N,N')(peroxodi-sulfato-κ²O,O')c

SUBMITTER: Harvey MA 

PROVIDER: S-EPMC5095838 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature